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AQA · GCSE · Chemistry · Higher

Using Rf to find solvent distance

Q04.2 4 marks

The blue colour moved 6.4 cm up the chromatogram.

The Rf value of the blue colour is 0.87.

Calculate the distance moved by the solvent. Give your answer to 2 significant figures.

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Marking points

  1. 1 Uses the Rf relationship with 0.87, 6.4 cm and the unknown solvent distance in the correct positions.
  2. 2 Rearranges to divide 6.4 by 0.87.
  3. 3 Obtains the unrounded value 7.356 (or the corresponding calculator value).
  4. 4 Gives 7.4 cm to 2 significant figures.

Full-mark answer

Rf = distance moved by colour ÷ distance moved by solvent, so 0.87 = 6.4 ÷ d. Therefore d = 6.4 ÷ 0.87 = 7.356… cm, which is 7.4 cm to 2 significant figures.

Why this answer loses marks

Rf is the solvent distance divided by the colour distance.

The ratio is inverted; start with colour distance divided by solvent distance before rearranging.